PHASE COMPOSITION AND MICROSTRUCTURE OF REACTIVE-BOUND MATERIALS BASED ON BORON CARBIDE


https://doi.org/10.17073/1683-4518-2018-4-96-100

Full Text:




Abstract

By the method of reaction impregnation with liquid silicon of porous boron carbide-based billets containing different amounts of carbon (0 to 15 wt. %), dense materials (ρ = 99,6 % of the theoretical value) were obtained from the initial B4C powders with d0.5 90 and 12,5 microns. The phase composition and the microstructure of the material were studied, the presence of the phase of a solid solution of boron carbide in silicon was determined. 


About the Authors

S. N. Perevislov
ФГБОУ ВО «Санкт-Петербургский государственный технологический институт (технический университет)»
Russian Federation


P. V. Shcherbak
ФГБОУ ВО «Санкт-Петербургский государственный технологический институт (технический университет)»
Russian Federation


M. V. Tomkovich
ФГБУН «Физико-технический институт имени А. Ф. Иоффе РАН»
Russian Federation


References

1. Aghajanian, M. K. A new family of reaction bonded ceramics for armor applications / M. K. Aghajanian, B. N. Morgan, J. R. Singh [et al.] // Ceram. Trans. ― 2002. ― Vol. 134. ― P. 527‒539.

2. Hayun, S. Dynamic Response of B4C‒SiC Ceramic Composites / S. Hayun, N. Frage, M. P. Dariel [et al.] // Ceramic Armor and Armor Systems II. ― 2006. ― Vol. 178. ― P. 147‒156.

3. Hayun, S. The morphology of ceramic phases in BxC‒SiC‒ Si infiltrated composites / S. Hayun, N. Frage, M. P. Dariel // J. Solid State Chem. ― 2006. ― Vol. 179, № 9. ― P. 2875‒2879.

4. Hayun, S. Static and dynamic mechanical properties of infiltrated B4C‒Si composites / S. Hayun, D. Rittel, N. Frage, M. P. Dariel // Mater. Sci. Eng., A. ― 2008. ― Vol. 487, № 1. ― P. 405‒409.

5. Suri, A. K. Synthesis and consolidation of boron carbide: a review / A. K. Suri, C. Subramanian, J. K. Sonber, T. C. Murthy // Int. Mater. Rev. ― 2010. ― Vol. 55, № 1. ― Р. 4‒40.

6. Zhang, C. P. Studies on the RBBC ceramics fabricated by reaction bonded SiC / C. P. Zhang, H. Q. Rue, X. Y. Yue, W. Wang // Rare Metal Mat. Eng. ― 2011. ― Vol. 40. ― Р. 536‒539.

7. Hayun, S. Microstructural evolution during the infiltration of boron carbide with molten silicon / S. Hayun, A. Weizmann, M. P. Dariel, N. Frage // J. Eur. Ceram. Soc. ― 2010. ― Vol. 30, № 4. ― P. 1007‒1014.

8. Hayun, S. The effect of carbon source on the microstructure and the mechanical properties of reaction bonded boron carbide / S. Hayun, H. Dilman, M. P. Dariel [et al.] // Adv. Sintering Sci. Technol. Ceram. Trans. ― 2010. ― Vol. 87. ― P. 29.

9. Barick, P. Effect of particle size on the mechanical properties of reaction bonded boron carbide ceramics / P. Barick, D. C. Jana, N. Thiyagarajan // Ceram. Int. ― 2013. ― Vol. 39, № 1. ― Р. 763‒770.

10. Golubeva, N. Study of reaction-bonded boron carbide properties / N. Golubeva, L. Plyasunkova, I. Kelina, E. Antonova, A. Zhuravlev // Refractories and Industrial Ceramics. ― 2015. ― Vol. 55, № 5. ― Р. 42‒46.

11. Sigl, L. S. Core/rim structure of liquid-phase-sintered silicon carbide / L. S. Sigl, H. J. Kleebe // J. Am. Ceram. Soc. ― 1993. ― Vol. 76. ― P. 773‒776.

12. Perevislov, S. N. Mechanism of liquid-phase sintering of silicon carbide and nitride with oxide activating additives / S. N. Perevislov // Glass Ceram. ― 2013. ― Vol. 70, № 7/8. ― Р. 265‒268.

13. Nesmelov, D. D. Reaction sintered materials based on boron carbide and silicon carbide / D. D. Nesmelov, S. N. Perevislov // Glass Ceram. ― 2015. ― Vol. 71, № 9/10. ― P. 313‒319.

14. Zhang, C. Coarsening of boron carbide grains during the infiltration of porous boron carbide preforms by molten silicon / C. Zhang, H. Ru, H. Zong [et al.] // Ceram. Int. ― 2016. ― Vol. 42, № 16. ― Р. 18681‒18691.

15. Li, X. Reaction-bonded B4C with high hardness / X. Li, D. Jiang, J. Zhang [et al.] // Int. J. Appl. Ceram. Technol. ― 2016. ― Vol. 13, № 3. ― Р. 584‒592.

16. Zheng, Y. Fabrication of nanocomposite Ti(C,N)-based cermet by spark plasma sintering / Y. Zheng, S. Wang, M. You [et al.] // Mater. Chem. Phys. ― 2005. ― Vol. 92, № 1. ― P. 64‒70.

17. Hayun, S. Rim region growth and its composition in reaction bonded boron carbide composites with core-rim structure / S. Hayun, A. Weizmann, H. Dilman [et al.] // J. Phys. Conf. Ser. ― 2009. ― Vol. 176, № 1. ― P. 012009.

18. Hayun, S. The effect of particle size distribution on the microstructure and the mechanical properties of boron carbide-based reaction-bonded composites / S. Hayun, A. Weizmann, M. P. Dariel, N. Frage // Int. J. Appl. Ceram. Technol. ― 2009. ― Vol. 6, № 4. ― P. 492‒500.

19. Perevislov, S. N. Effect of Si additions on the microstructure and mechanical properties of hot-pressed B4C / S. N. Perevislov, A. S. Lysenkov, S. V. Vikhman // Inorg. Mater. ― 2017. ― Vol. 53, № 4. ― P. 376‒380.

20. Perevislov, S. N. Properties of SiC and Si3N4 based composite ceramic with nanosize component / S. N. Perevislov, D. D. Nesmelov // Glass Ceram. ― 2016. ― Vol. 73, № 7/8. ― P. 249‒252.

21. Perevislov, S. N. Hot-pressed ceramic SiC‒YAG materials / S. N. Perevislov, A. S. Lysenkov, D. D. Titov, M. V. Tomkovich // Inorg. Mater. ― 2017. ― Vol. 53, № 2. ― P. 206‒211.

22. Kargin, Yu. F. Microstructure and properties of silicon nitride ceramics with calcium aluminate additions / Yu. F. Kargin, A. S. Lysenkov, S. N. Ivicheva [et al.] // Inorg. Mater. ― 2010. ― Vol. 46, № 7. ― P. 799‒803.

23. Kargin, Yu. F. Hot-pressed Si3N4 ceramics containing CaO‒Al2O3‒AlN modifying additives / Yu. F. Kargin, A. S. Lysenkov, S. N. Ivicheva [et al.] // Inorg. Mater. ― 2012. ― Vol. 48, № 11. ― P. 1158‒1163.

24. Sirota, V. Microstructural and physical properties of magnesium oxide-doped silicon nitride ceramics / V. Sirota, O. Lukianova, V. Krasilnikov [et al.] // Results in Physics. ― 2016. ― Vol. 6. ― Р. 82, 83.

25. 25. Chen, L. Fundamentalsofliquidphasesinteringformodern cermets and functionally graded cemented carbonitrides (FGCC) / L. Chen, W. Lengauer, P. Ettmayer [et al.] // Int. J. Refract. Met. Hard Mater. ― 2000. ― Vol. 18, № 6. ― P. 307‒322.

26. Frage, N. The effect of the sintering atmosphere on the densification of B4C ceramics / N. Frage, L. Levin, M. P. Dariel // J. Solid State Chem. ― 2004. ― Vol. 177, № 2. ― P. 410‒414.

27. Mallick, D. Development of multi-phase B‒Si‒C ceramic composite by reaction sintering / D. Mallick, T. K. Kayal, J. Ghosh [et al.] // Ceram. Int. ― 2009. ― Vol. 35, № 4. ― Р. 1667‒1669.

28. Dariel, M. P. Reaction bonded boron carbide: recent developments / M. P. Dariel, N. Frage // Adv. Appl. Ceram. ― 2012. ― Vol. 111, № 5/6. ― Р. 301‒310.


Supplementary files

For citation: Perevislov S.N., Shcherbak P.V., Tomkovich M.V. PHASE COMPOSITION AND MICROSTRUCTURE OF REACTIVE-BOUND MATERIALS BASED ON BORON CARBIDE. NOVYE OGNEUPORY (NEW REFRACTORIES). 2018;(4):96-100. https://doi.org/10.17073/1683-4518-2018-4-96-100

Views: 454

Refbacks

  • There are currently no refbacks.


ISSN 1683-4518 (Print)