RhEOLOGIE OF hIGh PERFORMANCE ALUMINA AND SPINEL CASTABLES


https://doi.org/10.17073/1683-4518-2017-3-119-126

Full Text:




Abstract

Cement-based refractory mixes  are used in a widespread range of applications and their share is still growing when compared to the total of refractory products. The satisfactory performance in use of castables is strongly dependent on their good workability for transport and casting. Poor flowability is often solved on site by high water additions. This, however, has a negative influence upon the desired properties. The developer of a refractory castable has to know the product properties he would like to achieve in the final application. This is taken into consideration when formulating to achieve good flowability. For example, this might be a matrix of a high alumina castable designed with high microsilica content to achieve mullite formation or a spinel containing castable for steel ladles where the use of reactive alumina is the only way to achieve high performance castables. The intention of this paper is not to suggest reactive alumina as the only solution for the design of high performance castables with good flowability. The focus is much more to provide a basic understanding of the impact of the matrix components on the rheology of castables with special focus on high performance alumina and spinel castables. Ill. 10. Ref. 19. Tab. 3.


About the Authors

M. Schnabel
Компания «Almatis GmbH»
Germany


A. Buhr
Компания «Almatis GmbH»
Germany


J. Dutton

United Kingdom


References

1. Informationsblatt Wirkmechanismen von Verf lüssigungs und Dispergiermitteln in keramischen Massen / Zschimmer & Schwarz GmbH & Co. KG.

2. Justnes, H. Viscosity of Cement Slurries as a Function of Solids Content / H. Justnes, H. Vikan // Annual Transactions of the Nordic Rheology Society. ― 2005. ― Vol. 13. ― P. 75‒82.

3. Ferraris, C. F. Measurement of the Rheological Properties of High Performance Concrete. State of the Art Report / C. F. Ferraris // Journal of Research of the National Institute of Standards and Technology. ― 1999. ― Vol. 104.

4. Hill, A. Understanding the Links between Rheology and Particle Parameters / A. Hill, S. Carrington //www. americanlaboratory.com ― 2006.

5. Seyerl von J. Chemical Additives for Castables / J. von Seyerl // UNITECR 2011, Kyoto, Japan. ― 1-D-11.

6. Clavaud, B. 15 Years of Low Cement Castables in Steelmaking / B. Clavaud, J. P. Kiehl, R. D. Schmidt-Whitley // First International Conference on Refractories, Tokyo, Japan. ― 1983. ― P. 589‒606.

7. Kriechbaum, G. The Matrix Advantage System, a new approach to low moisture LC self leveling alumina and alumina spinel castables / G. Kriechbaum, I. Stinnessen, V. Gnauck, J. O. Laurich [et al.] // 39. International Colloquium on Refractories, Aachen, Germany. ― 1996. ― P. 211‒218.

8. McConnell, R. W. Responding to the refractory industry’s need for fully ground matrix aluminas / R. W. McConnell, A. Fullington // UNITECR 2001, Cancun, Mexico. ― P. 768‒780.

9. Kockegey-Lorenz, R. Aluminas for Easy to Use High Performance Castables / R. Kockegey-Lorenz, D. Schmidtmeier, A. Buhr [et al.] // 53 International Colloquium on Refractories, Aachen, Germany. ― 2009. ― P. 86‒88.

10. Kockegey-Lorenz, R. Review of matrix aluminas for refractory formulations / R. Kockegey-Lorenz, A. Buhr [et al.] // UNITECR 2011, Kyoto, Japan.

11. Myhre, B. The effect of particle-size distribution on f low of refractory castables / B. Myhre // 30th Annual symposium of the American ceramic society, St. Louis. ― 1994.

12. Eguchi, T. Low-Cement-Bonded Castable Refractories / T. Eguchi [et al.] // Taikabutsu Overseas. ― 1989. ― Vol. 9, № 1. ― P. 10‒25.

13. Zeta Potential. Technical article / Ceram Research Ltd. // www.azom.com. –2001.

14. Myhre, B. Hot Strength and Bond-Phase Reactions in Low and Ultralow-cement castables / B. Myhre // UNITECR 1993, Sao Paulo, Brazil. ― P. 583‒594.

15. Kriechbaum, G. The Inf luence of SiO2 and Spinel on the hot Properties of High Alumina Low Cement Castables / G. Kriechbaum, V. Gnauck, G. Routschka // 37 International Colloquium on Refractories, Aachen, Germany. ― 1994. ― P. 150‒159.

16. Kopanda, J. E. Production Processes, Properties and Applications for Calcium Aluminate Cements / J. E. Kopanda, G. MacZura // Alumina Chemicals Handbook. ― 1990. ― P. 171‒183.

17. Braulio, M. A. L. Microsilica effects on cement bonded alumina-magnesia refractory castables / M. A. L. Braulio, L. R. M. Bittencourt, J. Porier, V. C. Pandolfelli // Journal of the Technical Association of Refractories, Japan. ― 2008. ― Vol. 28, № 3. ― P. 180‒184.

18. Buhr, A. Tonerdereiche Feuerfestbetone für den Einsatz in der Stahlindustrie (High AluminaRefractory Castables for Use in the Steel Industry) / A. Buhr // Stahl und Eisen. ― 1996. ― Vol. 116, № 9. ― P. 59‒66.

19. Schnabel, M. Spinel: in-situ versus preformed– clearingthemyth / M. Schnabel, A. Buhr, R. Exenberger, C. Rampitsch // Ref ractor ies World For um. ― 2010. ― Vol. 2. ― P. 87‒93.


Supplementary files

For citation: Schnabel M., Buhr A., Dutton J. RhEOLOGIE OF hIGh PERFORMANCE ALUMINA AND SPINEL CASTABLES. NOVYE OGNEUPORY (NEW REFRACTORIES). 2017;(3):119-126. https://doi.org/10.17073/1683-4518-2017-3-119-126

Views: 636

Refbacks

  • There are currently no refbacks.


ISSN 1683-4518 (Print)