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Synthesis of boron carbide powder using an indirect plasma torch and investigation of the properties of a composite based on it


https://doi.org/10.17073/1683-4518-2024-9-36-43

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Abstract

Boron carbide B4C powders were obtained by a vacuum-free method using an indirect plasma torch. The dependences of the effect of the duration of plasma exposure from 60 to 180 s and the mass of the charge containing boron and carbon powders from 0.5 to 1.5 g on the phase composition of the synthesis product are investigated. A composite based on synthesized boron carbide with the addition of silicon carbide in an  amount  of  15  %  was  consolidated by spark plasma sintering. The mechanical and thermophysical properties of the B4C‒15 % SiC composite have been studied. In addition, the oxidative properties of the resulting composite in the range of 300-900 °C have been studied. Ill. 8. Ref. 29. Tab. 1.


About the Authors

Yu. Z. Vasil’eva
ФГАОУ «Национальный исследовательский Томский политехнический университет»
Russian Federation


Zh. S. Bolatova
ФГАОУ «Национальный исследовательский Томский политехнический университет»
Russian Federation


R. D. Gerasimov
ФГАОУ «Национальный исследовательский Томский политехнический университет»; ФГБОУ ВО «Томский государственный архитектурно-строительный университет»
Russian Federation


V. V. Shekhovtsov
ФГБОУ ВО «Томский государственный архитектурно-строительный университет»
Russian Federation


A. Ya. Pak
ФГАОУ «Национальный исследовательский Томский политехнический университет»
Russian Federation


References

1. Radev, D. D. Classical and contemporary synthesis methods of boron carbide powders / D. D. Radev, E. Ampaw // Comptes Rendus. ― 2015. ― Vol. 68, № 8. ― P. 945‒956.

2. Gao, S. A low cost, low energy, environmentally friendly process for producing high-purity boron carbide / S. Gao, X. Li, Sh. Wang [et al.] // Ceram. Int. ― 2019. ― Vol. 45, № 3. ― P. 3101‒3110.

3. Vijay, S. K. Synthesis of nanocrystalline boron carbide by sucrose precursor method-optimization of process conditions / S. K. Vijay, R. Krishnaprabhu, Ch. Varadarajan, S. Anthonysamy // Ceram. Int. ― 2018. ― Vol. 44, № 5. ― P. 4676‒4684.

4. Suri, A. K. Synthesis and consolidation of boron carbide: а review / A. K. Suri, C. Subramanian, J. K. Sonber [et al.] // Int. Mater. Rev. ― 2010. ― Vol. 55, № 1. ― P. 4‒38.

5. Wang, J. Initial investigation of B4C‒TiB2 composites as neutron absorption material for nuclear reactors / J. Wang, D. Ren, L. Chen [et al.] // J. Nucl. Mater. ― 2020. ― Vol. 539. ― Article 152275.

6. Chen, Y. Boron carbide and boron carbonitride thin films as protective coatings in ultra-high density hard disk drives / Y. Chen, Y.-W. Chung, Sh.-Y. Li // Surface and Coatings Technology. ― 2006. ― Vol. 200, № 12/13. ― P. 4072‒4077.

7. Thévenot, F. Boron carbide: а comprehensive review / F. Thévenot // J. Eur. Ceram. Soc. ― 1990. ― Vol. 6, № 4. ― P. 205‒225.

8. Gao, Y. Processing factors influencing the free carbon contents in boron carbide powder by rapid carbothermal reduction / Y. Gao, A. Etzold, T. Munhollon [et al.] // Diam. Relat. Mater. ― 2016. ― Vol. 61. ― P. 14‒20.

9. Ramos, A. S. High-energy ball milling of powder B‒C mixtures / A. S. Ramos, S. P. Taguchi, E. C. T. Ramos [et al.] // Mater. Sci. Eng. A. ― 2006. ― Vol. 422, № 1/2. ― P. 184‒188.

10. Samal, S. Thermal plasma technology: the prospective future in material processing / S. Samal // J. Clean. Prod. ― 2017. ― Vol. 142. ― P. 3131‒3150.

11. Arora, N. Arc discharge synthesis of carbon nanotubes: сomprehensive review / N. Arora, N. N. Sharma // Diam. Relat. Mater. ― 2014. ― Vol. 50. ― P. 135‒150.

12. Pak, A. Cubic SiC nanowire synthesis by DC arc discharge under ambient air conditions / A. Pak, A. Ivashutenko, A. Zakharova, Y. Vassilyeva // Surf. Coat. Technol. ― 2020. ― Vol. 387. ― Article 125554.

13. Vassilyeva, Y. Z. Synthesis of Mo2C-based material in DC arc discharge plasma under ambient air conditions / Y. Z. Vassilyeva, K. B. Larionov, S. D. Afonnikova [et al.] // Mater. Chem. Phys. ― 2023. ― Article 128805.

14. Gerasimov, R. D. On the possibility of synthesis of silicon carbide using an indirect-action plasma gun / R. D. Gerasimov, V. V. Shekhovtsov, Yu. Z. Vasil’eva [et al.] // J. Eng. Phys. Thermophys. ― 2024. ― Vol. 97, № 2. ― P. 463‒470.

15. Zhang, W. Progress in pressureless sintering of boron carbide ceramics: a review / W. Zhang, S. Yamashita, H. Kita // Adv. Appl. Ceram. ― 2019. ― Vol. 118, № 4. ― P. 222‒239.

16. Ekici, E. The machinability of Al/B4C composites produced by hot pressing based on reinforcing the element ratio / E. Ekici, M. Gülesin // Sci. Eng. Compos. Mater. ― 2016. ― Vol. 23, № 6. ― P. 743‒750.

17. Xiong, Y. Densification mechanism during reactive hot pressing of B4C‒ZrO2 mixtures / Y. Xiong, X. Du, M. Xiang [et al.] // J. Eur. Ceram. Soc. ― 2018. ― Vol. 38, № 12. ― P. 4167‒4172.

18. Wen, Q. High toughness and electrical discharge machinable B4C‒TiB2‒SiC composites fabricated at low sintering temperature / Q. Wen, Y. Tan, Zh. Zhong [et al.] // Mater. Sci. Eng. A. ― 2017. ― Vol. 701, № 6. ― P. 338‒343.

19. Malmal Moshtaghioun, B. Toughening of superhard ultra-fine grained B4C densified by spark-plasma sintering via SiC addition / B. Malmal Moshtaghioun, A. L. Ortiz, D. Gómez-García, A. Domínguez-Rodríguez // J. Eur. Ceram. Soc. ― 2013. ― Vol. 33, № 8. ― P. 1395‒1401.

20. Zhang, X. Densification behaviour and mechanical properties of B4C‒SiC intergranular/intragranular nanocomposites fabricated through spark plasma sintering assisted by mechanochemistry / X. Zhang, Zh. Zhang, W. Weimin [et al.] // Ceram. Int. ― 2017. ― Vol. 43, № 2. ― P. 1904‒1910.

21. Uehara, M. SiC‒B4C composites for synergistic enhancement of thermoelectric property / M. Uehara, R. Shiraishi, A. Nogami [et al.] // J. Eur. Ceram. Soc. ― 2004. ― Vol. 24, № 2. ― P. 409‒412.

22. Thévenot, F. Sintering of boron carbide and boron carbide ‒ silicon carbide two-phase materials and their properties / F. Thévenot // J. Nucl. Mater. ― 1988. ― Vol. 152, № 2/3. ― P. 154‒162.

23. Zorzi, J. E. Hardness and wear resistance of B4C ceramics prepared with several additives / J. E. Zorzi, C. A. Perottoni, J. A. H. Da Jornada // Mater. Lett. ― 2005. ― Vol. 59, № 23. ― P. 2932‒2935.

24. Anselmi-Tamburini, U. Influence of synthesis temperature on the defect structure of boron carbide: Experimental and modeling studies / U. AnselmiTamburini, Z. A. Munir, Ya. Kodera [et al.] // J. Am. Ceram. Soc. ― 2005. ― Vol. 88, № 6. ― P. 1382‒1387.

25. Xu, H. Microstructural evolution in liquid-phasesintered SiC : Part I, Effect of starting powder / H. Xu, T. Bhatia, S. A. Deshpande [et al.] // J. Am. Ceram. Soc. ― 2001. ― Vol. 84, № 7. ― P. 1578‒1584.

26. Najafi, A. A novel route to obtain B4C nano powder via sol-gel method / A. Najafi, F. Golestani-Fard, H. R. Rezaie, N. Ehsani // Ceram. Int. ― 2012. ― Vol. 38, № 5. ― P. 3583‒3589.

27. Sahin, F. C. Spark plasma sintering of B4C‒SiC composites / F. C. Sahin, B. Apak, I. Akin [et al.] // Solid State Sci. ― 2012. ― Vol. 14, № 11/12. ― P. 1660‒1663.

28. Aygüzer, Yaşar Z. Improving fracture toughness of B4C‒SiC composites by TiB2 addition / Yaşar Z. Aygüzer, A. M. Celik, R. A. Haber // Int. J. Refract. Met. Hard Mater. ― 2022. ― Vol. 108, № 6.

29. Song, Q. Microstructure and self-healing mechanism of B4C‒TiB2‒SiC composite ceramic after pre-oxidation behaviour / Q. Song, Z. H. Zhang // Ceram. Int. ― 2022. ― Vol. 48, № 17. ― P. 25458‒25464.


Supplementary files

For citation: Vasil’eva Y.Z., Bolatova Z.S., Gerasimov R.D., Shekhovtsov V.V., Pak A.Y. Synthesis of boron carbide powder using an indirect plasma torch and investigation of the properties of a composite based on it. NOVYE OGNEUPORY (NEW REFRACTORIES). 2024;(9):36-43. https://doi.org/10.17073/1683-4518-2024-9-36-43

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