Open Access Open Access  Restricted Access Subscription Access

Using the surface energy of nanoparticles to produce high-strength concrete


https://doi.org/10.17073/1683-4518-2023-8-21-27

Full Text:




Abstract

The article considers a method for activating cement hardening processes using nanomaterials due to the magnitude of their surface energy: when injected into concrete, nanoparticles dump it due to the desire to transition to a stable state. Such activity leads to a significant gain in strength, hardness and the production of high-strength concrete. It is shown that such an effect can be achieved by surface impregnation of concrete with sols (colloidal solutions) based on SiO2 nanoparticles. It is advisable to start impregnation from the third day of hardening under normal conditions. At this age, the main heat of the cement's own exothermic hardening reaction has already been released into the environment, and the introduction of additional energy will not cause a shift in equilibrium towards slowing down the hardening processes in accordance with the Le-Chatelier principle. The results of physico-chemical studies of concrete after hardening, explaining this effect, are presented.


About the Author

A. M. Sycheva
Военно-космическая академия имени А. Ф. Можайского
Russian Federation
St. Petersburg


References

1. Sychova, A. M. Modification of fillers for cements. Book Chapter Electron Beam Modification of Solids: Mechanisms, Common Features and Promising Applications / A. M. Sychova, L. B. Svatovskaya, S. V. Mjakin, I. V. Vasiljeva. ― 2009. ― P. 35‒37.

2. Svatovskaya, L. B. Soling, aerating and phosphating for soil strengthening and detoxication / L. B. Svatovskaya, A. A. Kabanov, M. M. Sychov // Procedia Engineering ― 2017. ― Vol. 189. ― P. 398‒403. DOI: 10.1016/j.proeng.2017.05.063.

3. Svatovskaya, L. B. Geoecoprotective technology of transport construction using silica sol absorption method / L. B. Svatovskaya, O. V. Urov, A. A. Kabanov // Procedia Engineering. ― 2017. ― Vol. 189. ― P. 454‒458. DOI: 10.1016/j.proeng.2017.05.073.

4. Yakovlev, G. I. Modification of cement matrix using carbon nanotube dispersions and nanosilica / G. I. Yakovlev, G. B Skripkiunas, I. S. Polianskich [et al.] // Procedia Engineering. ― 2017. ― Vol. 172. ― P. 1261‒1269.

5. Danoglidis, P. A. Reinforcing concrete with carbon nanotubes and carbon nanofibers: a novel method to improve the modulus of elasticity / P. A. Danoglidis, M. S. Konsta-Gdoutos // ICTAEM 2018: Proceedings of the First International Conference on Theoretical, Applied and Experimental Mechanics. ― Р. 98, 99.

6. Yakovleva, G. Modification of construction materials with multi-walled carbon nanotubes / G. Yakovleva, G. Pervushina, I. Maeva [et al.] // Procedia Engineering. ― 2013. ― Vol. 57. ― P. 407‒413.

7. Niewiadomskia, P. Modern Building Materials, Structures and Techniques / P. Niewiadomskia, D. Stefaniuka, J. Hołaa // Procedia Engineering. ― 2017. ― Vol. 172. ― P. 776‒783.

8. Ślosarczyk, A. Influence of selected metal oxides in micro and nanoscale on the mechanical and physical properties of the cement mortars / A. Ślosarczyk, A. Kwiecińska, E. Pełszyk // Procedia Engineering. ― 2017. ― Vol. 172. ― P. 1031‒1038.

9. Nazari, Ali. TiO2 nanoparticles effects on physical, thermal and mechanical properties of self compacting concrete with ground granulated blast furnace slag as binder / Ali Nazari, Shadi Riahi // Energy and Buildings. ― 2011. ― Vol. 43. ― P. 995‒1002.

10. Nazari, Ali. Al2O3 nanoparticles in concrete and different curing media / Ali Nazari, Shadi Riahi // Energy and Buildings. ― 2011. ― Vol. 43. ― P. 1480‒1488.

11. Nazari, Ali. Splitting tensile strength of concrete using ground granulated blast furnace slag and SiO2 nanoparticles as binder / Ali Nazari, Shadi Riahi // Energyand Buildings. ― 2011. ― Vol. 43. ― P. 864‒872.

12. Riahi, Shadi. Physical, mechanical and thermal properties of concrete in different curing media containing ZnO2 nanoparticles / Shadi Riahi, Ali Nazari // Energy and Buildings. ― 2011. ― Vol. 43. ― P. 1977‒1984.

13. Yanturina, R. A. The influence of graphite-containing nano-additives on thermo frost resistance of concrete / R. A. Yanturina, B. Ya. Trofimova, R. M. Ahmedjanov // Procedia Engineering. ― 2017. ― Vol. 206. ― P. 869‒874.

14. Sychova, A. M. The improving of the concrete quality in a monolithic clip / A. M. Sychova, L. B. Svatovskaya, D. S. Starchukov [et al.] // Magazine of Civil Engineering. ― № 04. ― P. 3‒14.

15. Starchukov, D. S. Engineering and chemical bases of high-strength concrete with sol-containing additives : Monograph / D. S. Starchukov, P. A. Kozin, I. V. Stepanova [et al.]. ― М. : Military Space Academy named after A. F. Mozhaisky, 2014. ― 108 p.

16. Butt, U. M. Chemical technology of binders / U. M. Butt, M. M. Sychov, V. V. Timashov. ― М. : Higher school, 1980. ― 472 p.

17. Sychov, M. M. Inorganic glues / M. M. Sychov. ― L. : Chemistry. 1986. ― 152 p.

18. Ayler, R. K. Colloidal chemistry of silica and silicates / R. K. Ayler. ― M. : Gosstroiizdat, 1959. ― 288 p.

19. Gorshkov, V. S. Methods of physical and chemical analysis of binders / V. S. Gorshkov, V. V. Timashev, V. G. Savelyev. ― M. : Higher school, 1981. ― 336 p.

20. Sychova, A. M. Synthesis of impact-resistant concrete surface through the use of colloidal solutions / A. M. Sychova, L. B. Svatovskaya, D. S. Starchukov [et al.] // Journal of Transport construction. ― № 6. ― P. 22‒25.


Supplementary files

For citation: Sycheva A.M. Using the surface energy of nanoparticles to produce high-strength concrete. NOVYE OGNEUPORY (NEW REFRACTORIES). 2023;(8):21-27. https://doi.org/10.17073/1683-4518-2023-8-21-27

Views: 105

Refbacks

  • There are currently no refbacks.


ISSN 1683-4518 (Print)