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Bulk solid state polyantimonic acid based proton conducting membranes
https://doi.org/10.17073/1683-4518-2022-2-45-50
Abstract
Bulk solid state polyantimonic acid (PAA) based proton conducting membranes were manufactured using inert polymeric binder via cold isostatic pressing. Precursor powders were obtained using the step aqueous hydrolysis of antimony pentacloride. X-Ray diffraction (XRD) data showed that hydrolysis results in the crystalline PAA with pyrochlore structure. The composition of the powder obtained via solid state synthesis corresponds to sodium antimonite having ilmenite structure. In the temperature range 293‒453 K the linear dependence of conductivity logarithm on the reverse temperature was obtained in air. Based on XRD and conductivity data the obtained solid state PAA based membranes are the prospective proton conductors having conductivity of 10‒4 S/m and activation energy of conductivity 0,395 eV. Ill. 5. Ref. 25.
About the Authors
O. Yu. KurapovaRussian Federation
A. A. Zaripov
Russian Federation
V. V. Pazheltsev
Russian Federation
A. G. Glukharev
Russian Federation
V. G. Konakov
Russian Federation
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Supplementary files
For citation: Kurapova O.Y., Zaripov A.A., Pazheltsev V.V., Glukharev A.G., Konakov V.G. Bulk solid state polyantimonic acid based proton conducting membranes. NOVYE OGNEUPORY (NEW REFRACTORIES). 2022;(2):45-50. https://doi.org/10.17073/1683-4518-2022-2-45-50
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