Investigation of gas-phase processes for the preparation of fiber-reinforced organomorphic ceramic composites with a SiC-matrix


https://doi.org/10.17073/1683-4518-2020-8-23-30

Full Text:




Abstract

The isothermal process of gas-phase chemical deposition for the compaction of organomorphic carbon-fiber preforms with a SiC-matrix obtained by carbonization of compressed fibers of oxidized polyacrylonitrile has been investigated. Their feature is high (up to 70 %) and uniform pore size (reduced pore diameter from several micrometers to several tens of micrometers) porosity. The problem of optimizing the technological parameters of the process of obtaining ceramic-matrix composites (CMC) was solved by a combination of experimental research and numerical modeling. Experimental samples of CMC were obtained using a non-halogen precursor of methylsilane CH3SiH3, and their residual porosity was determined. For the numerical study of the gas-phase process of compaction of preforms, a 1D model was used. The simulation results were compared with experimental observations.


About the Authors

E. A. Bogachev
АО «Композит»
Russian Federation


V. I. Kulik
ФГБОУ ВПО «Балтийский государственный технический университет «ВОЕНМЕХ» имени Д. Ф. Устинова»
Russian Federation


A. V. Kulik
АО «Группа СТР»
Russian Federation


A. S. Nilov
ФГБОУ ВПО «Балтийский государственный технический университет «ВОЕНМЕХ» имени Д. Ф. Устинова»
Russian Federation


References

1. Bogachev, E. A. Design, structure and properties of organomorphic composites as new materials / E. A. Bogachev // Ceram. Int. ― 2019. ― Vol. 45. ― P. 9537-9543.

2. Garshin, A. P. Contemporary technology for preparing fiber-reinforced composite materials with a ceramic refractory matrix (review) / A. P. Garshin, V. I. Kulik, S. A. Matveev, A. S. Nilov // Refract. Ind. Ceram. ― 2017. ― Vol. 58, № 2. ― P. 148-161. Гаршин, А. П. Современные технологии получения волокнисто-армированных композиционных материалов с керамической огнеупорной матрицей (Обзор) / А. П. Гаршин, В. И. Кулик, С. А. Матвеев, А. С. Нилов // Новые огнеупоры. ― 2017. ― № 4. ― С. 20-35.

3. Hanbook of ceramic composites ; ed. by P. Narottam. ― Bansal. ― Boston, Dordrecht, London : Kluver Academic Publishers, 2005. ― Р. 554.

4. Heidenreich, B. C/SiC and C/C-SiC composites // in Ceramic matrix composites: materials, modelling and technology ; ed. by Bansal, Narottam P., Lamon J. / John Wiley & Sons, Inc., Hoboken, NJ, USA, 2014. ― P. 147-216.

5. Timofeev, А. Composites with silicon carbide matrix obtained from monomethylsilane by CVI method / A. Timofeev, E. Bogachev, A. Lahin // Proceedings of the 5th International Conference on High-Temperature Ceramic Matrix Composites, HTCMC-5, Seattle (WA). ― 2004. ― P. 87-90.

6. Bogachev, E. A. MMS Technology: first results and prospects / E. A. Bogachev, A. V. Lahin, A. N. Timofeev // Ceram. Trans. ― 2014. ― Vol. 248. ― P. 243-253.

7. Chang, H.-C. Minimizing infiltration times during isothermal chemical vapor infiltration with methyltrichlorsilane / H.-C. Chang, T. F. Morse, B. W. Sheldon // J. Am. Ceram. Soc. ― 1997. ― Vol. 80. ― Р. 1805-1811.

8. Kulik, V. I. Modelling of SiC-matrix composite formation by thermal gradient chemical vapour infiltration / V. I. Kulik, A. V. Kulik, M. S. Ramm, Yu. N. Makarov // Mater. Sci. Forum. ― 2004. ― Vol. 457-460. ― P. 253-256.

9. Kulik, V. I. Modeling of SiC-matrix composite formation by isothermal chemical vapour infiltration / V. I. Kulik, A. V. Kulik, M. S. Ramm, Yu. N. Makarov // J. Crystal Growth. ― 2004. ― Vol. 266. ― P. 333-339.

10. Пат. 2620810 RF. Method of manufacturing of porous preform ― basis of a composite material / Bogachev E. A., Elakov A. B., Beloglazov A. P., Denisov Yu. A., Timofeev A. N. ; appl. 06.05.16 ; dated 29.05.17, Bul. № 16.

11. Kogan, E. V. Porous structure of carbon–carbon friction composites studiedby gas adsorption and standard contact porosimetry techniques / E. V. Kogan, Yu. M. Volfkovich, V. V. Kulakov [et al.] // Inorganic Materials. ― 2012. ― Vol. 48. ― P. 676-679.

12. Кулик, В. И. Исследование термоградиентных процессов газофазного насыщения SiC-матрицей сложнопористых волокнистых каркасов с 3D-структурой / В. И. Кулик, А. В. Кулик, М. С. Рамм // Сб. трудов 1-го российского науч.-техн. симпозиума. «Интеллектуальные композиционные материалы и конструкции». ― М. : МГТУ им. Н. Э. Баумана, 2004. ― С. 36-41.

13. Лапин, Ю. В. Внутренние течения газовых смесей / Ю. В. Лапин, М. Х. Стрелец. ― М. : Наука, 1989. ― 368 с.

14. Оран Э. Численное моделирование реагирующих потоков / Э. Оран, Дж. Борис. ― М. : Мир, 1990. ― 660 с.

15. Патанкар, С. Численные методы решения задач теплообмена и динамики жидкости : пер. с англ. / С. Патанкар. ― М. : Энергоатомиздат, 1984. ― 152 с.

16. Johnson, A. D. Kinetics of SiC CVD: surface decomposition of silacyclobutane and methylsilane / A. D. Johnson, J. Perrin, J. A. Mucha, D. E. Ibbotson // J. Phys. Chem. ― 1993. ― Vol. 97, № 49. ― P. 12937-12948.

17. Ohshita, Y. Reactants in SiC chemical vapor deposition using CH3SiH3 as a source gas / Y. Ohshita // J. Cryst. Growth. ― 1995. ― Vol. 147, № 1/2. ― P. 111-116.

18. Tago, T. Numerical simulation of the thermalgradient chemical vapor infiltration process for production of fiber-reinforced ceramic composite / T. Tago, M. Kawase, Y. Ikuta, K. Hashimoto // Chemical Engineering Science. ― 2001. ― Vol. 56. ― P. 2161-2170.


Supplementary files

For citation: Bogachev E.A., Kulik V.I., Kulik A.V., Nilov A.S. Investigation of gas-phase processes for the preparation of fiber-reinforced organomorphic ceramic composites with a SiC-matrix. NOVYE OGNEUPORY (NEW REFRACTORIES). 2020;(8):23-30. https://doi.org/10.17073/1683-4518-2020-8-23-30

Views: 294

Refbacks

  • There are currently no refbacks.


ISSN 1683-4518 (Print)